Lithium diorganocuprate reactions with l-serine derivatives

The lithium diorganocuprate reactions with L-serine derivatives are studied. Retention of configuration, or at least a high enantiomeric excess (>80%) of the formed α-amino esters is observed in all cases. Attempts are made to restrict side-reactions.

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Bibliographische Detailangaben
Veröffentlicht in:	Tetrahedron letters 1984, Vol.25 (26), p.2759-2762
Hauptverfasser:	Bajgrowicz, J.A., El Hallaoui, A., Jacquier, R., Pigière, Ch, Viallefont, Ph
Format:	Artikel
Sprache:	eng
Schlagworte:	Aliphatic compounds Chemistry Exact sciences and technology L-serine lithium diorganocuprate Organic chemistry Preparations and properties
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The lithium diorganocuprate reactions with L-serine derivatives are studied. Retention of configuration, or at least a high enantiomeric excess (>80%) of the formed α-amino esters is observed in all cases. Attempts are made to restrict side-reactions.
ISSN:	0040-4039 1873-3581
DOI:	10.1016/S0040-4039(01)81283-1