Use of structure-reactivity relationships to estimate hydrolytic persistence of carbamate pesticides
Linear free energy relationships are given for use in estimating alkaline hydrolysis of carbamate pesticides in water as applied to environmental conditions. Plots of the second-order alkaline hydrolysis rate constants versus p K a of the resulting alcohol are given for N, N-dimethyl-, N-methyl- N-p...
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| Veröffentlicht in: | Water research (Oxford) 1978, Vol.12 (8), p.561-563 |
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| Sprache: | eng |
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| container_end_page | 563 |
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| container_issue | 8 |
| container_start_page | 561 |
| container_title | Water research (Oxford) |
| container_volume | 12 |
| creator | Lee Wolfe, N. Zepp, Richard G. Paris, Doris F. |
| description | Linear free energy relationships are given for use in estimating alkaline hydrolysis of carbamate pesticides in water as applied to environmental conditions. Plots of the second-order alkaline hydrolysis rate constants versus p
K
a of the resulting alcohol are given for
N,
N-dimethyl-,
N-methyl-
N-phenyl-,
N-methyl-, and
N-phenyl-carbamates. Use of these relationships allows one to estimate rate constants for specific compounds and make general statements about hydrolytic stability of classes of compounds. |
| doi_str_mv | 10.1016/0043-1354(78)90133-1 |
| format | Article |
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K
a of the resulting alcohol are given for
N,
N-dimethyl-,
N-methyl-
N-phenyl-,
N-methyl-, and
N-phenyl-carbamates. Use of these relationships allows one to estimate rate constants for specific compounds and make general statements about hydrolytic stability of classes of compounds.</description><identifier>ISSN: 0043-1354</identifier><identifier>EISSN: 1879-2448</identifier><identifier>DOI: 10.1016/0043-1354(78)90133-1</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><ispartof>Water research (Oxford), 1978, Vol.12 (8), p.561-563</ispartof><rights>1978</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c335t-e85da8896bdd5b39afe1382ce869966a2972c0a478cff423eb1ff25480ba6cdb3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/0043135478901331$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,4010,27900,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Lee Wolfe, N.</creatorcontrib><creatorcontrib>Zepp, Richard G.</creatorcontrib><creatorcontrib>Paris, Doris F.</creatorcontrib><title>Use of structure-reactivity relationships to estimate hydrolytic persistence of carbamate pesticides</title><title>Water research (Oxford)</title><description>Linear free energy relationships are given for use in estimating alkaline hydrolysis of carbamate pesticides in water as applied to environmental conditions. Plots of the second-order alkaline hydrolysis rate constants versus p
K
a of the resulting alcohol are given for
N,
N-dimethyl-,
N-methyl-
N-phenyl-,
N-methyl-, and
N-phenyl-carbamates. Use of these relationships allows one to estimate rate constants for specific compounds and make general statements about hydrolytic stability of classes of compounds.</description><issn>0043-1354</issn><issn>1879-2448</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1978</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWKv_wMOeRA-r-drd5CJI8QsKXuw5ZJMJjWybNckW-u_dbcWjp2HgmXd4H4SuCb4nmNQPGHNWElbx20bcSUzYuJ2gGRGNLCnn4hTN_pBzdJHSF8aYUiZnyK4SFMEVKcfB5CFCGUGb7Hc-74sInc4-bNPa96nIoYCU_UZnKNZ7G0O3z94UPcTkU4atOQQZHVt9YPqJNt5CukRnTncJrn7nHK1enj8Xb-Xy4_V98bQsDWNVLkFUVgsh69baqmVSOyBMUAOilrKuNZUNNVjzRhjnOGXQEudoxQVudW1sy-bo5pjbx_A9jO_VxicDXae3EIakCJO0orQaQX4ETQwpRXCqj2OxuFcEq0mpmnypyZdqhDooHbc5ejyewVhi5yGqZPxU3PoIJisb_P8BP7OEgIE</recordid><startdate>1978</startdate><enddate>1978</enddate><creator>Lee Wolfe, N.</creator><creator>Zepp, Richard G.</creator><creator>Paris, Doris F.</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope></search><sort><creationdate>1978</creationdate><title>Use of structure-reactivity relationships to estimate hydrolytic persistence of carbamate pesticides</title><author>Lee Wolfe, N. ; Zepp, Richard G. ; Paris, Doris F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c335t-e85da8896bdd5b39afe1382ce869966a2972c0a478cff423eb1ff25480ba6cdb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1978</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lee Wolfe, N.</creatorcontrib><creatorcontrib>Zepp, Richard G.</creatorcontrib><creatorcontrib>Paris, Doris F.</creatorcontrib><collection>CrossRef</collection><collection>Aqualine</collection><jtitle>Water research (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lee Wolfe, N.</au><au>Zepp, Richard G.</au><au>Paris, Doris F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Use of structure-reactivity relationships to estimate hydrolytic persistence of carbamate pesticides</atitle><jtitle>Water research (Oxford)</jtitle><date>1978</date><risdate>1978</risdate><volume>12</volume><issue>8</issue><spage>561</spage><epage>563</epage><pages>561-563</pages><issn>0043-1354</issn><eissn>1879-2448</eissn><abstract>Linear free energy relationships are given for use in estimating alkaline hydrolysis of carbamate pesticides in water as applied to environmental conditions. Plots of the second-order alkaline hydrolysis rate constants versus p
K
a of the resulting alcohol are given for
N,
N-dimethyl-,
N-methyl-
N-phenyl-,
N-methyl-, and
N-phenyl-carbamates. Use of these relationships allows one to estimate rate constants for specific compounds and make general statements about hydrolytic stability of classes of compounds.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/0043-1354(78)90133-1</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0043-1354 |
| ispartof | Water research (Oxford), 1978, Vol.12 (8), p.561-563 |
| issn | 0043-1354 1879-2448 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_13925225 |
| source | Elsevier ScienceDirect Journals |
| title | Use of structure-reactivity relationships to estimate hydrolytic persistence of carbamate pesticides |
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