Degradation of the tri-n-butyltin species in water
To assess the aqueous persistence of bis(tri-n-butyltin)oxide some basic physical and chemical properties of tri-n-butyltin species were investigated. In the dark at 20C there was no volatilization of the tri-n-butyltin from water, nor any loss of butyl groups over the study period of 63 days occurr...
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Veröffentlicht in: | Journal of agricultural and food chemistry 1983-09, Vol.31 (5), p.1060-1065 |
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container_title | Journal of agricultural and food chemistry |
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creator | Maguire, R. James Carey, John H Hale, Elizabeth J |
description | To assess the aqueous persistence of bis(tri-n-butyltin)oxide some basic physical and chemical properties of tri-n-butyltin species were investigated. In the dark at 20C there was no volatilization of the tri-n-butyltin from water, nor any loss of butyl groups over the study period of 63 days occurred. Photolysis was slow with a half-life of over 89 days. The octanol-water partition coefficient at pH6 and 20C was 3.2. For bis(tri-n-butyltin)oxide, vapour pressure was estimated at 0.00000064 mm Hg. |
doi_str_mv | 10.1021/jf00119a035 |
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James ; Carey, John H ; Hale, Elizabeth J</creator><creatorcontrib>Maguire, R. James ; Carey, John H ; Hale, Elizabeth J</creatorcontrib><description>To assess the aqueous persistence of bis(tri-n-butyltin)oxide some basic physical and chemical properties of tri-n-butyltin species were investigated. In the dark at 20C there was no volatilization of the tri-n-butyltin from water, nor any loss of butyl groups over the study period of 63 days occurred. Photolysis was slow with a half-life of over 89 days. The octanol-water partition coefficient at pH6 and 20C was 3.2. 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James</creatorcontrib><creatorcontrib>Carey, John H</creatorcontrib><creatorcontrib>Hale, Elizabeth J</creatorcontrib><title>Degradation of the tri-n-butyltin species in water</title><title>Journal of agricultural and food chemistry</title><addtitle>J. Agric. Food Chem</addtitle><description>To assess the aqueous persistence of bis(tri-n-butyltin)oxide some basic physical and chemical properties of tri-n-butyltin species were investigated. In the dark at 20C there was no volatilization of the tri-n-butyltin from water, nor any loss of butyl groups over the study period of 63 days occurred. Photolysis was slow with a half-life of over 89 days. The octanol-water partition coefficient at pH6 and 20C was 3.2. 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Food Chem</addtitle><date>1983-09</date><risdate>1983</risdate><volume>31</volume><issue>5</issue><spage>1060</spage><epage>1065</epage><pages>1060-1065</pages><issn>0021-8561</issn><eissn>1520-5118</eissn><abstract>To assess the aqueous persistence of bis(tri-n-butyltin)oxide some basic physical and chemical properties of tri-n-butyltin species were investigated. In the dark at 20C there was no volatilization of the tri-n-butyltin from water, nor any loss of butyl groups over the study period of 63 days occurred. Photolysis was slow with a half-life of over 89 days. The octanol-water partition coefficient at pH6 and 20C was 3.2. For bis(tri-n-butyltin)oxide, vapour pressure was estimated at 0.00000064 mm Hg.</abstract><pub>American Chemical Society</pub><doi>10.1021/jf00119a035</doi><tpages>6</tpages></addata></record> |
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title | Degradation of the tri-n-butyltin species in water |
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