Determination of mercury in seawater at sub-nanogram per liter levels

Using a refined two-stage gold amalgamation preconcentration technique in conjunction with cold vapor atomic absorption (CVAA) detection, mercury in various Pacific Northwest coastal waters has been determined. Through the use of extremely clean reagents and special handling techniques, the blank has been reduced and reproducibility greatly improved for both “easily reducible mercury” and “total mercury”. Samples of unfiltered water, taken at the surface, as well as at 10 m, 100 m, and 175 m have all yielded “easily reducible mercury” at between 0.1 and 0.5 ng l −1, and “total mercury” between 0.2 and 1.0 ng l −1. Variability within replicate field samples is less than 10%, although variations of greater than 100% may be seen over a period of hours in Sequim Bay.