Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P sub(4) cage and P sub(8) clusters

The reaction of cyclic di(amido)- and (alkyl)(amino)-carbenes with white phosphorus in benzene afford P sub(8) clusters supported by four carbenes, or a novel type of carbene-P sub(4) adduct.

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2013-04, Vol.49 (40), p.4486-4488
Hauptverfasser:	Martin, Caleb D, Weinstein, Cory M, Moore, Curtis E, Rheingold, Arnold L, Bertrand, Guy
Format:	Artikel
Sprache:	eng
Schlagworte:	Adducts Benzene Cage Carbenes Clusters Phosphorus Synthesis
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creator	Martin, Caleb D Weinstein, Cory M Moore, Curtis E Rheingold, Arnold L Bertrand, Guy
description	The reaction of cyclic di(amido)- and (alkyl)(amino)-carbenes with white phosphorus in benzene afford P sub(8) clusters supported by four carbenes, or a novel type of carbene-P sub(4) adduct.
doi_str_mv	10.1039/c3cc42041h
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identifier	ISSN: 1359-7345
ispartof	Chemical communications (Cambridge, England), 2013-04, Vol.49 (40), p.4486-4488
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language	eng
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source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Adducts Benzene Cage Carbenes Clusters Phosphorus Synthesis
title	Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P sub(4) cage and P sub(8) clusters
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