Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P sub(4) cage and P sub(8) clusters

Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P sub(4) cage and P sub(8) clusters

The reaction of cyclic di(amido)- and (alkyl)(amino)-carbenes with white phosphorus in benzene afford P sub(8) clusters supported by four carbenes, or a novel type of carbene-P sub(4) adduct.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-04, Vol.49 (40), p.4486-4488
Hauptverfasser: Martin, Caleb D, Weinstein, Cory M, Moore, Curtis E, Rheingold, Arnold L, Bertrand, Guy
Format: Artikel
Sprache:eng
Schlagworte:
Adducts
Benzene
Cage
Carbenes
Clusters
Phosphorus
Synthesis
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Beschreibung
Zusammenfassung:The reaction of cyclic di(amido)- and (alkyl)(amino)-carbenes with white phosphorus in benzene afford P sub(8) clusters supported by four carbenes, or a novel type of carbene-P sub(4) adduct.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc42041h