Effect of pore sizes on catalytic activities of arenetricarbonyl metal complexes constructed within Zr-based MOFs

Effect of pore sizes on catalytic activities of arenetricarbonyl metal complexes constructed within Zr-based MOFs

Arenetricarbonyl metal complexes ([-phM(CO)3-] and [-biphM(CO)3-]; ph = phenylene, biph = biphenylene, M = Mo, Cr) constructed within Zr-based MOFs act as highly active and selective catalysts for epoxidation of cyclooctene. Catalytic activities of these complexes are enhanced with increasing the po...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2013-07, Vol.42 (26), p.9444-9447
Hauptverfasser: Saito, Masakazu, Toyao, Takashi, Ueda, Kozo, Kamegawa, Takashi, Horiuchi, Yu, Matsuoka, Masaya
Format: Artikel
Sprache:eng
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Zusammenfassung:Arenetricarbonyl metal complexes ([-phM(CO)3-] and [-biphM(CO)3-]; ph = phenylene, biph = biphenylene, M = Mo, Cr) constructed within Zr-based MOFs act as highly active and selective catalysts for epoxidation of cyclooctene. Catalytic activities of these complexes are enhanced with increasing the pore sizes of Zr-based MOFs.
ISSN:1477-9226
1477-9234
DOI:10.1039/c3dt50593f