Chemoselective, iron(II)-catalyzed oxidation of a variety of secondary alcohols over primary alcohols utilizing H2O2 as the oxidant

Chemoselective, iron(II)-catalyzed oxidation of a variety of secondary alcohols over primary alcohols utilizing H2O2 as the oxidant

A mild, iron-based catalyst system is presented that selectively oxidizes secondary alcohols to the corresponding hydroxy ketones in the presence of primary alcohols within 15 minutes at room temperature, utilizing H2O2 as the oxidant.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (52), p.5889-5891
Hauptverfasser: Lenze, Matthew, Bauer, Eike B
Format: Artikel
Sprache:eng
Schlagworte:
Alcohols - chemistry
Catalysis
Coordination Complexes - chemistry
Ferrous Compounds - chemistry
Hydrogen Peroxide - chemistry
Ketones - chemistry
Oxidation-Reduction
Temperature
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Beschreibung
Zusammenfassung:A mild, iron-based catalyst system is presented that selectively oxidizes secondary alcohols to the corresponding hydroxy ketones in the presence of primary alcohols within 15 minutes at room temperature, utilizing H2O2 as the oxidant.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc41131a