A Solid-Contact Ion Selective Electrode for Copper(II) Using a Succinlmide Derivative as lonophore

All-solid-state sensors with polyvinyl chloride (PVC)-based membranes using off-the-shelf N-hydroxysuccinimide (NHS) and succinimide (Succ) ionophores were prepared using DOP (dioctyl phthalate) and NPOE (ortho-nitrophenyloctyl ether) as plasticizers. Good responses were obtained when NHS was used. The potentiometric response of the proposed electrode is independent of pH over the range 2-6. The electrode shows a fast response time of 0.25 s. The electrode exhibits a Super-Nemstian response, with 37.5 mV/decade, with a potentiometric detection limit of 4.4 mu M. The proposed sensor revealed good selectivity towards a group of transition metal ions.