Synergetic catalysis of ceria and titania for selective reduction of NO

The promotional effect of the interaction between titania and ceria on the catalytic performance for selective reduction of NO was studied.The catalysts,CeO 2,TiO 2,CeO 2 /TiO 2 and Ti x Ce 1-x O 2,were synthesized and tested in NH 3-Selective catalytic reduction(SCR) of NO,and the samples were char...

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Veröffentlicht in:Journal of rare earths 2012-05, Vol.30 (5), p.431-436
1. Verfasser: 沈岳松 郑大海 杨波 倪松波 祝社民
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container_title Journal of rare earths
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creator 沈岳松 郑大海 杨波 倪松波 祝社民
description The promotional effect of the interaction between titania and ceria on the catalytic performance for selective reduction of NO was studied.The catalysts,CeO 2,TiO 2,CeO 2 /TiO 2 and Ti x Ce 1-x O 2,were synthesized and tested in NH 3-Selective catalytic reduction(SCR) of NO,and the samples were characterized by the Brunaller,Emmett and Teller(BET absorbed gas N 2),X-ray diffraction(XRD),high resolution transmission electron microscopy(HR-TEM),and temperature programmed desorption(TPD NH 3) techniques.The improvement mechanism of the interaction between the titania and ceria had been explored and discussed from two aspects of micro-structure and surface acidity.The interaction between the titania and ceria greatly improved the catalytic activity but had little effect on the active temperature.It was first reported that the acid amount determined the catalytic activity and the acid strength determined the active temperature for NH 3-SCR of NO.
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subjects Catalysis
Catalysts
Catalytic activity
Cerium oxide
Diffraction
interaction between ceria and titania
NO conversion
Rare earth metals
rare earths
Reduction
selective catalytic reduction
synergetic catalysis
Titanium dioxide
二氧化钛
催化性能
氧化铈
相互作用机制
选择性催化还原
选择性还原
高分辨透射电子显微镜
title Synergetic catalysis of ceria and titania for selective reduction of NO
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