Synergetic catalysis of ceria and titania for selective reduction of NO

The promotional effect of the interaction between titania and ceria on the catalytic performance for selective reduction of NO was studied.The catalysts,CeO 2,TiO 2,CeO 2 /TiO 2 and Ti x Ce 1-x O 2,were synthesized and tested in NH 3-Selective catalytic reduction(SCR) of NO,and the samples were char...

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Veröffentlicht in:Journal of rare earths 2012-05, Vol.30 (5), p.431-436
1. Verfasser: 沈岳松 郑大海 杨波 倪松波 祝社民
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Sprache:eng
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Zusammenfassung:The promotional effect of the interaction between titania and ceria on the catalytic performance for selective reduction of NO was studied.The catalysts,CeO 2,TiO 2,CeO 2 /TiO 2 and Ti x Ce 1-x O 2,were synthesized and tested in NH 3-Selective catalytic reduction(SCR) of NO,and the samples were characterized by the Brunaller,Emmett and Teller(BET absorbed gas N 2),X-ray diffraction(XRD),high resolution transmission electron microscopy(HR-TEM),and temperature programmed desorption(TPD NH 3) techniques.The improvement mechanism of the interaction between the titania and ceria had been explored and discussed from two aspects of micro-structure and surface acidity.The interaction between the titania and ceria greatly improved the catalytic activity but had little effect on the active temperature.It was first reported that the acid amount determined the catalytic activity and the acid strength determined the active temperature for NH 3-SCR of NO.
ISSN:1002-0721
2509-4963
DOI:10.1016/S1002-0721(12)60067-2