Subsolidus phase relations in the SrOaCuOaTiO2 ternary system at 950 degree C in air
We report the subsolidus phase relations in the SrOaCuOaTiO2 ternary system at 950 degree C in air. For this study, numerous samples of various nominal compositions were prepared by the solid state reaction, and their equilibrium phases were analyzed by powder X-ray diffraction (XRD). On the basis o...
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Veröffentlicht in: | Journal of alloys and compounds 2013-04, Vol.556, p.210-213 |
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creator | Lee, Sung-Yun Kim, Hui Eun Yoo, Sang-Im |
description | We report the subsolidus phase relations in the SrOaCuOaTiO2 ternary system at 950 degree C in air. For this study, numerous samples of various nominal compositions were prepared by the solid state reaction, and their equilibrium phases were analyzed by powder X-ray diffraction (XRD). On the basis of our XRD analysis data and previous reports on the SrOaCuO, CuOaTiO2, and SrOaTiO2 binary phase diagrams, subsolidus phase diagram of the SrOaCuOaTiO2 ternary system could be completely constructed. Instead of the stoichiometric SrCu3Ti4O12 compound, new ternary compounds of Sr0.9639(1-y)Cu3.0361(1-3y)Ti4+2yO12-type solid solutions were found to exist and their solubility limit was 0 |
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For this study, numerous samples of various nominal compositions were prepared by the solid state reaction, and their equilibrium phases were analyzed by powder X-ray diffraction (XRD). On the basis of our XRD analysis data and previous reports on the SrOaCuO, CuOaTiO2, and SrOaTiO2 binary phase diagrams, subsolidus phase diagram of the SrOaCuOaTiO2 ternary system could be completely constructed. Instead of the stoichiometric SrCu3Ti4O12 compound, new ternary compounds of Sr0.9639(1-y)Cu3.0361(1-3y)Ti4+2yO12-type solid solutions were found to exist and their solubility limit was 0 <= y <= 0.0235 at 950 degree C in air.</description><identifier>ISSN: 0925-8388</identifier><language>eng</language><subject>Alloys ; Binary systems ; Diffraction ; Phase diagrams ; Solid solutions ; Solubility ; Ternary systems ; X-rays</subject><ispartof>Journal of alloys and compounds, 2013-04, Vol.556, p.210-213</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785</link.rule.ids></links><search><creatorcontrib>Lee, Sung-Yun</creatorcontrib><creatorcontrib>Kim, Hui Eun</creatorcontrib><creatorcontrib>Yoo, Sang-Im</creatorcontrib><title>Subsolidus phase relations in the SrOaCuOaTiO2 ternary system at 950 degree C in air</title><title>Journal of alloys and compounds</title><description>We report the subsolidus phase relations in the SrOaCuOaTiO2 ternary system at 950 degree C in air. For this study, numerous samples of various nominal compositions were prepared by the solid state reaction, and their equilibrium phases were analyzed by powder X-ray diffraction (XRD). On the basis of our XRD analysis data and previous reports on the SrOaCuO, CuOaTiO2, and SrOaTiO2 binary phase diagrams, subsolidus phase diagram of the SrOaCuOaTiO2 ternary system could be completely constructed. Instead of the stoichiometric SrCu3Ti4O12 compound, new ternary compounds of Sr0.9639(1-y)Cu3.0361(1-3y)Ti4+2yO12-type solid solutions were found to exist and their solubility limit was 0 <= y <= 0.0235 at 950 degree C in air.</description><subject>Alloys</subject><subject>Binary systems</subject><subject>Diffraction</subject><subject>Phase diagrams</subject><subject>Solid solutions</subject><subject>Solubility</subject><subject>Ternary systems</subject><subject>X-rays</subject><issn>0925-8388</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqVjrsOgjAUQDtoIj7-4Y4uJC0EpTPRuDHATq5ylZrysLcd-Hs18QecznJOchYikjrJ4jzN85VYMz-llEqnKhJ1Fa48WtMGhqlDJnBk0ZtxYDAD-I6gciUWocTalAl4cgO6GXhmTz2gB51JaOnhiKD4JmjcVizvaJl2P27E_nyqi0s8ufEViH3TG76RtTjQGLhR6SFT6qg_S3-obyEZQnc</recordid><startdate>20130415</startdate><enddate>20130415</enddate><creator>Lee, Sung-Yun</creator><creator>Kim, Hui Eun</creator><creator>Yoo, Sang-Im</creator><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20130415</creationdate><title>Subsolidus phase relations in the SrOaCuOaTiO2 ternary system at 950 degree C in air</title><author>Lee, Sung-Yun ; Kim, Hui Eun ; Yoo, Sang-Im</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_miscellaneous_13651179193</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Alloys</topic><topic>Binary systems</topic><topic>Diffraction</topic><topic>Phase diagrams</topic><topic>Solid solutions</topic><topic>Solubility</topic><topic>Ternary systems</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lee, Sung-Yun</creatorcontrib><creatorcontrib>Kim, Hui Eun</creatorcontrib><creatorcontrib>Yoo, Sang-Im</creatorcontrib><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of alloys and compounds</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lee, Sung-Yun</au><au>Kim, Hui Eun</au><au>Yoo, Sang-Im</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Subsolidus phase relations in the SrOaCuOaTiO2 ternary system at 950 degree C in air</atitle><jtitle>Journal of alloys and compounds</jtitle><date>2013-04-15</date><risdate>2013</risdate><volume>556</volume><spage>210</spage><epage>213</epage><pages>210-213</pages><issn>0925-8388</issn><abstract>We report the subsolidus phase relations in the SrOaCuOaTiO2 ternary system at 950 degree C in air. For this study, numerous samples of various nominal compositions were prepared by the solid state reaction, and their equilibrium phases were analyzed by powder X-ray diffraction (XRD). On the basis of our XRD analysis data and previous reports on the SrOaCuO, CuOaTiO2, and SrOaTiO2 binary phase diagrams, subsolidus phase diagram of the SrOaCuOaTiO2 ternary system could be completely constructed. Instead of the stoichiometric SrCu3Ti4O12 compound, new ternary compounds of Sr0.9639(1-y)Cu3.0361(1-3y)Ti4+2yO12-type solid solutions were found to exist and their solubility limit was 0 <= y <= 0.0235 at 950 degree C in air.</abstract></addata></record> |
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subjects | Alloys Binary systems Diffraction Phase diagrams Solid solutions Solubility Ternary systems X-rays |
title | Subsolidus phase relations in the SrOaCuOaTiO2 ternary system at 950 degree C in air |
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