Temperature dependences of density of sodium borosilicate glasses in equilibrium states at temperatures below a vitrification temperature

The temperature dependences of the density and intensity of SAXRS of a variety of sodium borosilicate glasses in equilibrium states below vitrification temperature are obtained. The existence of a transition of the investigated supercooled liquids in a solid noncrystalline state was discovered that...

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Veröffentlicht in:Glass physics and chemistry 2013, Vol.39 (1), p.11-18
Hauptverfasser: Golubkov, V. V., Onushchenko, P. A.
Format: Artikel
Sprache:eng
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Zusammenfassung:The temperature dependences of the density and intensity of SAXRS of a variety of sodium borosilicate glasses in equilibrium states below vitrification temperature are obtained. The existence of a transition of the investigated supercooled liquids in a solid noncrystalline state was discovered that is similar to the one observed in the study of vitreous boron oxide and alkali-borate glasses. The temperature of the transition of supercooled liquids of the investigated compositions to a solid noncrystalline state is about 50°C below the vitrification temperatures determined by the SAXRS data. Thus, the transition occurs at a viscosity of 1014 P in borate and sodium borosilicate glasses.
ISSN:1087-6596
1608-313X
DOI:10.1134/S1087659613010070