Photocatalytic Degradation of Lindane in Aqueous Solution

Photolysis of lindane in aqueous solution, using near‐visible and UV light (λ >320 nm) and in the presence of the polyoxometallate PW12O403‐, results in its conversion to CO2 and HCl. Initial photodecomposition takes place within a few minutes both in the presence and absence of dioxygen. The eff...

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Veröffentlicht in:Pesticide Science 1997-06, Vol.50 (2), p.171-174
Hauptverfasser: Hiskia, Anastasia, Mylonas, Athanasios, Tsipi, Despina, Papaconstantinou, Elias
Format: Artikel
Sprache:eng
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Zusammenfassung:Photolysis of lindane in aqueous solution, using near‐visible and UV light (λ >320 nm) and in the presence of the polyoxometallate PW12O403‐, results in its conversion to CO2 and HCl. Initial photodecomposition takes place within a few minutes both in the presence and absence of dioxygen. The effective mineralization in the absence of dioxygen suggests that OH radicals act as the primary oxidant in this case.
ISSN:0031-613X
1526-498X
1096-9063
DOI:10.1002/(SICI)1096-9063(199706)50:2<171::AID-PS565>3.0.CO;2-H