Efficient fixation of atmospheric CO2 as carbonate by lanthanide-based complex via synergistic effect of zinc ion

Efficient fixation of atmospheric CO2 as carbonate by lanthanide-based complex via synergistic effect of zinc ion

Reactions of [Zn(L)(H2O)] precursor and EuCl3 with the aid of CO3(2-) ions derived from atmospheric CO2 affording an unusual heteropolynuclear cluster [Zn4L4Eu4(CO3)6]·EtOH. In the core of the cluster, four hetero-binuclear [ZnLEu] units linked by six CO3(2-) anions forms a well defined [Zn4Eu4] ske...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2013-06, Vol.42 (24), p.8571-8574
Hauptverfasser: Zhang, Bin, Zheng, Xiaodu, Su, Hao, Zhu, Yu, Du, Chenxia, Song, Maoping
Format: Artikel
Sprache:eng
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Zusammenfassung:Reactions of [Zn(L)(H2O)] precursor and EuCl3 with the aid of CO3(2-) ions derived from atmospheric CO2 affording an unusual heteropolynuclear cluster [Zn4L4Eu4(CO3)6]·EtOH. In the core of the cluster, four hetero-binuclear [ZnLEu] units linked by six CO3(2-) anions forms a well defined [Zn4Eu4] skeleton with good planarity, which plays an important role in stabilizing the cluster.
ISSN:1477-9226
1477-9234
DOI:10.1039/c3dt50230a