Molecular amino-phosphonate cobalt-lanthanide clusters

The use of 1-amino-1-cyclohexyl phosphonic acid, a functionalised phosphonate, leads to the synthesis of two new structural types for 3d-4f phosphonate cages with unusual structural cores and which show high magnetocaloric effects.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-05, Vol.49 (34), p.3522-3524
Hauptverfasser: Moreno Pineda, Eufemio, Tuna, Floriana, Pritchard, Robin G, Regan, Andrew C, Winpenny, Richard E P, McInnes, Eric J L, Zheng, Yan-Zhen
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Sprache:eng
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Zusammenfassung:The use of 1-amino-1-cyclohexyl phosphonic acid, a functionalised phosphonate, leads to the synthesis of two new structural types for 3d-4f phosphonate cages with unusual structural cores and which show high magnetocaloric effects.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc40907d