Oxidative Addition of a Strained C–C Bond onto Electron-Rich Rhodium(I) at Room Temperature

Oxidative Addition of a Strained C–C Bond onto Electron-Rich Rhodium(I) at Room Temperature

The C–C bond of cyclobutanones undergoes oxidative addition to a T-shape rhodium(I) complex possessing a PBP pincer ligand at room temperature. The remarkable propensity of the rhodium complex for oxidative addition is attributed to the highly electron-donating nature of the boron ligand as well as...

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Veröffentlicht in:Journal of the American Chemical Society 2013-05, Vol.135 (19), p.7142-7145
Hauptverfasser: Masuda, Yusuke, Hasegawa, Maki, Yamashita, Makoto, Nozaki, Kyoko, Ishida, Naoki, Murakami, Masahiro
Format: Artikel
Sprache:eng
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Zusammenfassung:The C–C bond of cyclobutanones undergoes oxidative addition to a T-shape rhodium(I) complex possessing a PBP pincer ligand at room temperature. The remarkable propensity of the rhodium complex for oxidative addition is attributed to the highly electron-donating nature of the boron ligand as well as the unsaturation on the rhodium center.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja403461f