RANEY® Ni catalyzed transfer hydrogenation of levulinate esters to γ-valerolactone at room temperature

A catalytic transfer hydrogenation process was developed for the production of γ-valerolactone (GVL) from ethyl levulinate (EL) and a H-donor at room temperature. Ethyl levulinate was almost quantitatively converted to γ-valerolactone. Further, a two step process for producing GVL from biomass deriv...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-06, Vol.49 (46), p.5328-5330
Hauptverfasser: Yang, Zhen, Huang, Yao-Bing, Guo, Qing-Xiang, Fu, Yao
Format: Artikel
Sprache:eng
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Zusammenfassung:A catalytic transfer hydrogenation process was developed for the production of γ-valerolactone (GVL) from ethyl levulinate (EL) and a H-donor at room temperature. Ethyl levulinate was almost quantitatively converted to γ-valerolactone. Further, a two step process for producing GVL from biomass derived platform molecules was also reported.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc40980e