Ru(II)-catalyzed intermolecular ortho-C-H amidation of aromatic ketones with sulfonyl azides

Ru(II)-catalyzed intermolecular ortho-C-H amidation of aromatic ketones with sulfonyl azides

Ru(II)-catalyzed intermolecular ortho-C-H amidation of weakly coordinating aromatic ketones with sulfonyl azides is reported. The developed reaction protocol can be extended to various substituted aromatic ketones to afford a wide range of desired C-N bond formation products in good yields.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-06, Vol.49 (45), p.5225-5227
Hauptverfasser: Bhanuchandra, M, Yadav, M Ramu, Rit, Raja K, Rao Kuram, Malleswara, Sahoo, Akhila K
Format: Artikel
Sprache:eng
Schlagworte:
Amides - chemistry
Azides - chemistry
Benzene Derivatives - chemistry
Catalysis
Ketones - chemistry
Ruthenium - chemistry
Stereoisomerism
Sulfinic Acids - chemistry
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Zusammenfassung:Ru(II)-catalyzed intermolecular ortho-C-H amidation of weakly coordinating aromatic ketones with sulfonyl azides is reported. The developed reaction protocol can be extended to various substituted aromatic ketones to afford a wide range of desired C-N bond formation products in good yields.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc41915k