Synthesis of substituted hydantoins in low melting mixtures

Synthesis of substituted hydantoins in low melting mixtures

A novel domino synthesis of 1,3,5-trisubstituted hydantoin derivatives has been developed in low melting L-(+)-tartaric acid-DMU melt mixtures. The functionalized hydantoins are obtained in good yields from β,γ-unsaturated ketoacids and urea under environmentally benign and simple reaction condition...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-06, Vol.49 (44), p.5052-5054
Hauptverfasser: Gore, Sangram, Chinthapally, Kiran, Baskaran, Sundarababu, König, Burkhard
Format: Artikel
Sprache:eng
Schlagworte:
Crystallography, X-Ray
Hydantoins - chemical synthesis
Hydantoins - chemistry
Molecular Conformation
Phase Transition
Solvents - chemistry
Tartrates - chemistry
Urea - chemistry
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Zusammenfassung:A novel domino synthesis of 1,3,5-trisubstituted hydantoin derivatives has been developed in low melting L-(+)-tartaric acid-DMU melt mixtures. The functionalized hydantoins are obtained in good yields from β,γ-unsaturated ketoacids and urea under environmentally benign and simple reaction conditions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc41254g