Studies of hybrid organic-inorganic [2] and [3]rotaxanes bound to Au surfaces

Studies of hybrid organic-inorganic [2] and [3]rotaxanes bound to Au surfaces

Hybrid organic-inorganic [2]- and [3]rotaxanes have been synthesised, and their ability to bind to Au surfaces studied; the length of the tethering group is found to control how the supramolecular assembly binds to the surface and we find that [2]rotaxanes show improved stability over previous studi...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (33), p.3404-3406
Hauptverfasser: Rath, Harapriya, Timco, Grigore A, Corradini, Valdis, Ghirri, Alberto, del Pennino, Umberto, Fernandez, Antonio, Pritchard, Robin G, Muryn, Christopher A, Affronte, Marco, Winpenny, Richard E P
Format: Artikel
Sprache:eng
Schlagworte:
Assembly
Control surfaces
Gold
Rings (mathematics)
Stability
Tethering
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Beschreibung
Zusammenfassung:Hybrid organic-inorganic [2]- and [3]rotaxanes have been synthesised, and their ability to bind to Au surfaces studied; the length of the tethering group is found to control how the supramolecular assembly binds to the surface and we find that [2]rotaxanes show improved stability over previous studies of simple inorganic rings.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc38699f