Suspended GaN nanowires as NO sub(2) sensor for high temperature applications

We propose a gas sensor operable over a wide temperature range and using suspended GaN nanowires functionalized with Pt-Pd. The sensor is batch-fabricated by directly integrating the GaN nanowires onto batch-processed silicon microelectrodes in parallel. The high thermal stability of the sensor orig...

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Veröffentlicht in:Analyst (London) 2013-03, Vol.138 (8), p.2432-2437
Hauptverfasser: Sim, Jaesam, Kim, Kwanoh, Song, Soonho, Kim, Jongbaeg
Format: Artikel
Sprache:eng
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Zusammenfassung:We propose a gas sensor operable over a wide temperature range and using suspended GaN nanowires functionalized with Pt-Pd. The sensor is batch-fabricated by directly integrating the GaN nanowires onto batch-processed silicon microelectrodes in parallel. The high thermal stability of the sensor originates from a large band gap of GaN nanowires that enables the detection of NO sub(2) gas at an elevated temperature of up to 350 degree C without a decrease in responsiveness. Exposed to NO sub(2) at 100-1000 ppm at 350 degree C, the sensor shows a linear increment in relative response with respect to the change in gas concentration. The sensor results in a two- to four-fold increase in responsiveness to NO sub(2) at 100 ppm compared to NH sub(3) at 100 ppm and CO sub(2) at 1000 ppm. The nanowires suspended over a substrate provide increased surface area that could interact with gas molecules for enhanced responsiveness, and prevent any unnecessary interactions between the nanowires and the substrate.
ISSN:0003-2654
1364-5528
DOI:10.1039/c3an36917j