Chiral aryl iodide catalysts for the enantioselective synthesis of para-quinols

Chiral aryl iodide catalysts for the enantioselective synthesis of para-quinols

Molecular modelling of an iodine(III) phenoxide was used as a starting point in the design of chiral aryl iodide catalysts for stereoselective oxidative dearomatization reactions. Using this approach, catalysts derived from 8-iodotetralone and tartaric acid were constructed and used to synthesize en...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (29), p.3001-3003
Hauptverfasser: Volp, Kelly A, Harned, Andrew M
Format: Artikel
Sprache:eng
Schlagworte:
Aromatic compounds
Catalysis
Catalysts
Iodides
Phenols
Synthesis
Tartaric acid
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Zusammenfassung:Molecular modelling of an iodine(III) phenoxide was used as a starting point in the design of chiral aryl iodide catalysts for stereoselective oxidative dearomatization reactions. Using this approach, catalysts derived from 8-iodotetralone and tartaric acid were constructed and used to synthesize enantioenriched para-quinols from phenols.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc00013c