Guided supramolecular polymerization of oligo(p-phenylenevinylene) functionalized bismelamines

Guided supramolecular polymerization of oligo(p-phenylenevinylene) functionalized bismelamines

Bismelamines end-functionalized with oligo(p-phenylenevinylene) self-aggregate in nonpolar solvent to form short nanorods by helical π-π stacking. This inherent self-aggregation can be guided to a supramolecular polymerization pathway by complexing with a cyanurate, leading to gel-forming elongated...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (43), p.4941-4943
Hauptverfasser: Yamauchi, Mitsuaki, Kubota, Shun, Karatsu, Takashi, Kitamura, Akihide, Ajayaghosh, Ayyappanpillai, Yagai, Shiki
Format: Artikel
Sprache:eng
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Zusammenfassung:Bismelamines end-functionalized with oligo(p-phenylenevinylene) self-aggregate in nonpolar solvent to form short nanorods by helical π-π stacking. This inherent self-aggregation can be guided to a supramolecular polymerization pathway by complexing with a cyanurate, leading to gel-forming elongated nanotapes lacking the helical sense of the π-conjugated moieties.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc41461b