Iron-catalyzed direct alkenylation of sp super(3)(C-H) bonds via decarboxylation of cinnamic acids under ligand-free conditions

Iron-catalyzed direct alkenylation of sp super(3)(C-H) bonds via decarboxylation of cinnamic acids under ligand-free conditions

An example of highly efficient low-cost ferrocene-catalyzed decarboxylative C(sp super(2))-C(sp super(3)) coupling reactions via C-H functionalization has been developed successfully. It is noteworthy that nanoparticles of Fe sub(3)O sub(4) could be used as a reusable catalyst for 7 times in the abs...

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2013-04, Vol.15 (4), p.976-981
Hauptverfasser: Yang, Hailong, Yan, Hong, Sun, Peng, Zhu, Yan, Lu, Linhua, Liu, Defu, Rong, Guangwei, Mao, Jincheng
Format: Artikel
Sprache:eng
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Zusammenfassung:An example of highly efficient low-cost ferrocene-catalyzed decarboxylative C(sp super(2))-C(sp super(3)) coupling reactions via C-H functionalization has been developed successfully. It is noteworthy that nanoparticles of Fe sub(3)O sub(4) could be used as a reusable catalyst for 7 times in the absence of ligand.
ISSN:1463-9262
1463-9270
DOI:10.1039/c3gc37131j