Improved thermooxidation and sedimentation stability of covalently-coated carbonyl iron particles with cholesteryl groups and their influence on magnetorheology

[Display omitted] ► Two-step covalent compact coating of CI particles. ► Smoother coated surface in comparison with bare one. ► Enhanced sedimentation stability and thermal stability in oxygen atmosphere. ► Favorable MR performance for suspensions containing 80wt.% of coated CI particles. Sedimentat...

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Veröffentlicht in:Journal of colloid and interface science 2013-04, Vol.396, p.146-151
Hauptverfasser: Mrlík, Miroslav, Ilčíková, Markéta, Pavlínek, Vladimír, Mosnáček, Jaroslav, Peer, Petra, Filip, Petr
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Sprache:eng
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Zusammenfassung:[Display omitted] ► Two-step covalent compact coating of CI particles. ► Smoother coated surface in comparison with bare one. ► Enhanced sedimentation stability and thermal stability in oxygen atmosphere. ► Favorable MR performance for suspensions containing 80wt.% of coated CI particles. Sedimentation of particles in magnetorheological suspensions represents a crucial problem that concerns their efficient long-term application in practice. Prepared carbonyl iron (CI) microparticles coated with a low density substance, cholesteryl chloroformate, via a two-step reaction and immersed in silicone oil, exhibit three positive aspects: (1) the CI particle modification increased the compatibility between the particles and the silicone oil resulting in improved long-term stability (reduction in sedimentation); (2) the coating provided the particles with enhanced thermal stability in the oxygen atmosphere; and (3) rheological measurements proved a promising magnetorheological performance at different particle weight fractions.
ISSN:0021-9797
1095-7103
DOI:10.1016/j.jcis.2013.01.027