Elastic electron scattering from water vapor and ice at high momentum transfer

We compare the area, peak separation, and width of the H and O elastic peak for light and heavy water, as observed in spectra of keV electrons scattered over large angles. Peak separation is well reproduced by the theory, but the O:H area ratio is somewhat larger than expected and is equal to the O:...

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Veröffentlicht in:The Journal of chemical physics 2013-01, Vol.138 (4), p.044307-044307
Hauptverfasser: Vos, M, Weigold, E, Moreh, R
Format: Artikel
Sprache:eng
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Zusammenfassung:We compare the area, peak separation, and width of the H and O elastic peak for light and heavy water, as observed in spectra of keV electrons scattered over large angles. Peak separation is well reproduced by the theory, but the O:H area ratio is somewhat larger than expected and is equal to the O:D area ratio. Thus no anomalous scattering from H was observed. Only minor differences are observed for scattering from a gaseous or a solid target. The extracted mean kinetic energy of H and D agreed within 5% with the calculated ones for ice. For the more difficult vapor measurements agreement was on a 12% level. A preliminary attempt to extract the O kinetic energy in ice agreed within 10% with the calculated values.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.4775810