Comparison of post-detonation combustion in explosives incorporating aluminum nanoparticles: Influence of the passivation layer

Aluminum nanoparticles and explosive formulations that incorporate them have been a subject of ongoing interest due to the potential of aluminum particles to dramatically increase energy content relative to conventional organic explosives. We have used time-resolved atomic and molecular emission spe...

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Veröffentlicht in:Journal of applied physics 2013-01, Vol.113 (4)
Hauptverfasser: Lewis, W. K., Rumchik, C. G., Smith, M. J., Fernando, K. A. S., Crouse, C. A., Spowart, J. E., Guliants, E. A., Bunker, C. E.
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Sprache:eng
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Zusammenfassung:Aluminum nanoparticles and explosive formulations that incorporate them have been a subject of ongoing interest due to the potential of aluminum particles to dramatically increase energy content relative to conventional organic explosives. We have used time-resolved atomic and molecular emission spectroscopy to monitor the combustion of aluminum nanoparticles within the overall chemical dynamics of post-detonation fireballs. We have studied the energy release dynamics of hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) charges incorporating three types of aluminum nanoparticles: commercial oxide-passivated nanoparticles, oleic acid-capped aluminum nanoparticles (AlOA), and nanoparticles in which the oxide shell of the particle has been functionalized with an acrylic monomer and copolymerized into a fluorinated acrylic matrix (AlFA). The results indicate that the commercial nanoparticles and the AlFA nanoparticles are oxidized at a similar rate, while the AlOA nanoparticles combust more quickly. This is most likely due to the fact that the commercial nano-Al and the AlFA particles are both oxide-passivated, while the AlOA particles are protected by an organic shell that is more easily compromised than an oxide layer. The peak fireball temperatures for RDX charges containing 20 wt. % of commercial nano-Al, AlFA, or AlOA were ∼3900 K, ∼3400 K, and ∼4500 K, respectively.
ISSN:0021-8979
1089-7550
DOI:10.1063/1.4790159