Fluorine interaction controlled AIEE phenomenon in an expanded calixbenzophyrin and its vapoluminescent response: turn on emission with volatile ketones and esters

Fluorine interaction controlled AIEE phenomenon in an expanded calixbenzophyrin and its vapoluminescent response: turn on emission with volatile ketones and esters

Fluorine interaction assisted AIEE characteristic in an expanded calixbenzophyrin is presented by single-crystal X-ray-diffraction analysis and molecular modelling approaches. Selective exposure to volatile organic compounds such as ketones and esters results in the breaking of fluorine interaction,...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-03, Vol.49 (22), p.2213-2215
Hauptverfasser: Salini, P S, Derry Holaday, M G, Reddy, M L P, Suresh, C H, Srinivasan, A
Format: Artikel
Sprache:eng
Schlagworte:
Calixarenes - chemistry
Crystallography, X-Ray
Emission
Emissions control
Esters
Esters - chemistry
Fluorine
Fluorine - chemistry
Ketones
Ketones - chemistry
Luminescence
Models, Molecular
Molecular Structure
Monomers
Organic compounds
Porphyrins - chemistry
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Beschreibung
Zusammenfassung:Fluorine interaction assisted AIEE characteristic in an expanded calixbenzophyrin is presented by single-crystal X-ray-diffraction analysis and molecular modelling approaches. Selective exposure to volatile organic compounds such as ketones and esters results in the breaking of fluorine interaction, leading to enhanced monomer emission.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc38723b