Conformationally restricted pyrrolidines by intramolecular [2+2] photocycloaddition reactions

Conformationally restricted pyrrolidines by intramolecular [2+2] photocycloaddition reactions

Intramolecular [2+2] photocycloaddition reactions of diversely substituted N-Boc protected 4-(allylaminomethyl)-2(5H)-furanones resulted in rigid products (53-75%) with three spatially defined positions for further functionalisation.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-04, Vol.49 (29), p.2989-2991
Hauptverfasser: Fort, Diego A, Woltering, Thomas J, Nettekoven, Matthias, Knust, Henner, Bach, Thorsten
Format: Artikel
Sprache:eng
Schlagworte:
Amines - chemistry
Azabicyclo Compounds - chemistry
Cycloaddition Reaction
Furans - chemistry
Heptanes - chemistry
Photochemical Processes
Pyrrolidines - chemistry
Stereoisomerism
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Zusammenfassung:Intramolecular [2+2] photocycloaddition reactions of diversely substituted N-Boc protected 4-(allylaminomethyl)-2(5H)-furanones resulted in rigid products (53-75%) with three spatially defined positions for further functionalisation.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc40757h