Lewis Basic Selenium Catalyzed Chloroamidation of Olefins Using Nitriles as the Nucleophiles

Lewis Basic Selenium Catalyzed Chloroamidation of Olefins Using Nitriles as the Nucleophiles

A Lewis base catalyzed chloroamidation of olefinic substrates was achieved using diphenyl selenide as the catalyst. The reaction conditions are mild and suitable for a wide range of substrates including those which are acid labile.

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Veröffentlicht in:Organic letters 2013-03, Vol.15 (6), p.1310-1313
Hauptverfasser: Tay, Daniel Weiliang, Tsoi, Ivan Tan, Er, Jun Cheng, Leung, Gulice Yiu Chung, Yeung, Ying-Yeung
Format: Artikel
Sprache:eng
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Zusammenfassung:A Lewis base catalyzed chloroamidation of olefinic substrates was achieved using diphenyl selenide as the catalyst. The reaction conditions are mild and suitable for a wide range of substrates including those which are acid labile.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol400249x