Gold catalyzed stereoselective tandem hydroamination-formal aza-Diels-Alder reaction of propargylic amino esters

Gold catalyzed stereoselective tandem hydroamination-formal aza-Diels-Alder reaction of propargylic amino esters

A gold-catalyzed tandem intramolecular hydroamination-formal aza-Diels-Alder reaction of propargylic amino esters is described. The overall process leads to the formation of a tetracyclic framework as a single diastereoisomer, with the creation of four bonds and five stereocenters.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-02, Vol.49 (13), p.1336-1338
Hauptverfasser: Fustero, Santos, Bello, Paula, Miró, Javier, Sánchez-Roselló, María, Maestro, Miguel A, González, Javier, del Pozo, Carlos
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Chemical bonds
Esters
Gold
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container_issue 13
container_start_page 1336
container_title Chemical communications (Cambridge, England)
container_volume 49
creator Fustero, Santos
Bello, Paula
Miró, Javier
Sánchez-Roselló, María
Maestro, Miguel A
González, Javier
del Pozo, Carlos
description A gold-catalyzed tandem intramolecular hydroamination-formal aza-Diels-Alder reaction of propargylic amino esters is described. The overall process leads to the formation of a tetracyclic framework as a single diastereoisomer, with the creation of four bonds and five stereocenters.
doi_str_mv 10.1039/c2cc37796a
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Chemical bonds
Esters
Gold
title Gold catalyzed stereoselective tandem hydroamination-formal aza-Diels-Alder reaction of propargylic amino esters
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