Rewriting the bacterial glycocalyx via Suzuki-Miyaura cross-coupling

Suzuki-Miyaura cross-coupling has been used to couple novel carbohydrate-based boronic acids, site-selectively, to the surface of E. coli at an unnatural amino acid. In this way, benign metal-catalyzed cellular switching allowed modulation of interactions with biomolecular partners via prokaryotic O...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (27), p.2747-2749
Hauptverfasser: Spicer, Christopher D, Davis, Benjamin G
Format: Artikel
Sprache:eng
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Zusammenfassung:Suzuki-Miyaura cross-coupling has been used to couple novel carbohydrate-based boronic acids, site-selectively, to the surface of E. coli at an unnatural amino acid. In this way, benign metal-catalyzed cellular switching allowed modulation of interactions with biomolecular partners via prokaryotic O-glycosylation mimics.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc38824g