Tetrabutylammonium iodide catalyzed allylic sulfonylation of Baylis-Hillman acetates with sulfonylhydrazides in water

A tetrabutylammonium iodide catalyzed method for the synthesis of allyl aryl sulfone derivatives with Baylis-Hillman acetates and sulfonylhydrazides using tert-butyl hydroperoxide as an oxidation agent in water has been developed. In this process, the group eliminated from the sulfonyl precursor is...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Organic & biomolecular chemistry 2013-02, Vol.11 (10), p.1739-1742
Hauptverfasser:	Li, Xiaoqing, Xu, Xiangsheng, Tang, Yucai
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetates - chemistry Allyl Compounds - chemical synthesis Allyl Compounds - chemistry Catalysis Hydrazines - chemistry Molecular Structure Quaternary Ammonium Compounds - chemistry Sulfones - chemical synthesis Sulfones - chemistry Water - chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	A tetrabutylammonium iodide catalyzed method for the synthesis of allyl aryl sulfone derivatives with Baylis-Hillman acetates and sulfonylhydrazides using tert-butyl hydroperoxide as an oxidation agent in water has been developed. In this process, the group eliminated from the sulfonyl precursor is molecular nitrogen.
ISSN:	1477-0520 1477-0539
DOI:	10.1039/c3ob27329f