Mesoporous iron oxide directly anchored on a graphene matrix for lithium-ion battery anodes with enhanced strain accommodation

A continuous mesoporous iron oxide nanofilm was directly formed on graphene nanosheets through the in situthermal decomposition of Fe(NO sub(3)) sub(3).9H sub(2)O and was anchored tightly on the graphene surface. The lithiation-induced strain was naturally accommodated, owing to the constraint effec...

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Veröffentlicht in:RSC advances 2013-01, Vol.3 (3), p.699-703
Hauptverfasser: Zheng, Mingbo, Qiu, Danfeng, Zhao, Bin, Ma, Luyao, Wang, Xinran, Lin, Zixia, Pan, Lijia, Zheng, Youdou, Shi, Yi
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Sprache:eng
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Zusammenfassung:A continuous mesoporous iron oxide nanofilm was directly formed on graphene nanosheets through the in situthermal decomposition of Fe(NO sub(3)) sub(3).9H sub(2)O and was anchored tightly on the graphene surface. The lithiation-induced strain was naturally accommodated, owing to the constraint effect of graphene and the mesoporous structure. Hence, the pulverization of the iron oxide nanofilm was effectively prevented.
ISSN:2046-2069
2046-2069
DOI:10.1039/C2RA22702A