Stitching together SN sub(x) units in the coordination sphere of zirconium: assembly of a tris(imido)sulfite and a hydrazidobis(imido)sulfite

Stitching together SN sub(x) units in the coordination sphere of zirconium: assembly of a tris(imido)sulfite and a hydrazidobis(imido)sulfite

Reaction of a zirconium imido and a hydrazinediido complex with bis(trimethylsilyl)sulfur diimide yielded the corresponding formal [2+2] cycloaddition products, the trisimidosulfito complex and the hydrazidobis(imido)sulfito complex containing an unprecedented SN sub(2)(N-N) unit.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-02, Vol.48 (18), p.2397-2399
Hauptverfasser: Gehrmann, Thorsten, Kruck, Matthias, Wadepohl, Hubert, Gade, Lutz H
Format: Artikel
Sprache:eng
Schlagworte:
Assembly
Cycloaddition
Diimide
Stitching
Zirconium
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Beschreibung
Zusammenfassung:Reaction of a zirconium imido and a hydrazinediido complex with bis(trimethylsilyl)sulfur diimide yielded the corresponding formal [2+2] cycloaddition products, the trisimidosulfito complex and the hydrazidobis(imido)sulfito complex containing an unprecedented SN sub(2)(N-N) unit.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc17594k