Kinetics of hydrogen abstraction by active metal hydroxo and oxo intermediates: revealing their unexpected similarities in the transition state

Kinetics of hydrogen abstraction by active metal hydroxo and oxo intermediates: revealing their unexpected similarities in the transition state

The kinetics of hydrogen abstraction by manganese(IV) species having hydroxo or oxo group reveals that they have very similar reactive characters in the transition state of hydrogen abstraction.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-08, Vol.48 (63), p.7832-7834
Hauptverfasser: Wang, Yujuan, Shi, Song, Wang, Huajun, Zhu, Dajian, Yin, Guochuan
Format: Artikel
Sprache:eng
Schlagworte:
Analogies
Reaction kinetics
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Zusammenfassung:The kinetics of hydrogen abstraction by manganese(IV) species having hydroxo or oxo group reveals that they have very similar reactive characters in the transition state of hydrogen abstraction.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc33615d