Synthesis and reactivity of cationic ruthenium germylene complexes [Cp(PiPr sub(3))RuH sub(2)(&z.dbd; GeRR')] super(+)

Synthesis and reactivity of cationic ruthenium germylene complexes [Cp(PiPr sub(3))RuH sub(2)(&z.dbd; GeRR')] super(+)

Two synthetic routes to cationic ruthenium germylene complexes are described. A hydrogen-substituted germylene complex undergoes various additions of the Ge-H bond to alkene and alkyne substrates.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-07, Vol.48 (62), p.7690-7692
Hauptverfasser: Fasulo, Meg E, Tilley, TDon
Format: Artikel
Sprache:eng
Schlagworte:
Alkynes
Bonding
Cationic
Olefins
Ruthenium
Synthesis
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Two synthetic routes to cationic ruthenium germylene complexes are described. A hydrogen-substituted germylene complex undergoes various additions of the Ge-H bond to alkene and alkyne substrates.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc32840b