Physical and Electrochemical Properties of Monofluorinated Ethyl Acetates for Lithium Rechargeable Batteries

Physical and Electrochemical Properties of Monofluorinated Ethyl Acetates for Lithium Rechargeable Batteries

Ethyl acetate (EA) shows low viscosity for its relative permittivity. Monofluorinated solvents exert the polar effect on the physical and electrochemical properties. Relative permittivity of 2-fluoroethyl acetate (2FEA) was lower than that of ethyl fluoroacetate (EFA), though viscosity of 2FEA was h...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Denki kagaku oyobi kōgyō butsuri kagaku 2010/05/05, Vol.78(5), pp.446-449
Hauptverfasser: NANBU, Noritoshi, SUZUKI, Yuta, OHTSUKI, Kiyoshi, MEGURO, Takeshi, TAKEHARA, Masahiro, UE, Makoto, SASAKI, Yukio
Format: Artikel
Sprache:eng
Schlagworte:
Anodic
Carboxylate
Cycles
Dielectric constant
Ethyl acetate
Ionic conductivity
Lithium
Lithium Battery
Monofluorinated Solvent
Position Isomerism
Solvents
Viscosity
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Ethyl acetate (EA) shows low viscosity for its relative permittivity. Monofluorinated solvents exert the polar effect on the physical and electrochemical properties. Relative permittivity of 2-fluoroethyl acetate (2FEA) was lower than that of ethyl fluoroacetate (EFA), though viscosity of 2FEA was higher. Ionic conductivity of 2FEA was lower than that of EFA, but higher than that of EA at high temperatures. The anodic stability of 2FEA and EFA was higher than that of EA. The use of 2FEA as a co-solvent improved cycling efficiency of a lithium anode.
ISSN:1344-3542
2186-2451
DOI:10.5796/electrochemistry.78.446