A triangulo palladium cluster consisting of [small mu ]3-capping silyl ligands

A triangulo palladium cluster consisting of [small mu ]3-capping silyl ligands

We report on the utility of multifunctional, [small kappa]1Si:[small kappa]3S-coordinated tris(methimazolyl)silanide ligands [Si(mtMe)3]- for the stabilisation of a triangulo palladium cluster [Pd3{Si(mtMe)3}2] (3) consisting of very unusual [small mu ]3-capping SiR3 donors. Differences to the corre...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (1), p.221-223
Hauptverfasser: Armbruster, Felix, Meyer, Jens, Baldes, Alexander, Burgos, Pascual Ona, Fernandez, Ignacio, Breher, Frank
Format: Artikel
Sprache:eng
Schlagworte:
Clusters
Ligands
Mathematical analysis
NMR spectroscopy
Palladium
Platinum
Utilities
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Zusammenfassung:We report on the utility of multifunctional, [small kappa]1Si:[small kappa]3S-coordinated tris(methimazolyl)silanide ligands [Si(mtMe)3]- for the stabilisation of a triangulo palladium cluster [Pd3{Si(mtMe)3}2] (3) consisting of very unusual [small mu ]3-capping SiR3 donors. Differences to the corresponding platinum chemistry were supported by NMR spectroscopy and DFT calculations.
ISSN:1359-7345
DOI:10.1039/C002435J