CO2 superabsorption in a paddlewheel-type Ru dimer chain compound: gate-open performance dependent on inter-chain interactions

A porous one-dimensional coordination chain compound, [Ru(2)(p-F-PhCO(2))(4)(phz)] (; p-F-PhCO(2)(-) = para-fluorobenzoate; phz = phenazine) derived by drying its nitrobenzene-solvated compound, specifically adsorbs CO(2) at 195 K in a stepwise sorption manner.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2013-02, Vol.49 (16), p.1594-1596
Hauptverfasser:	Kosaka, Wataru, Yamagishi, Kayo, Yoshida, Hiroki, Matsuda, Ryotaro, Kitagawa, Susumu, Takata, Masaki, Miyasaka, Hitoshi
Format:	Artikel
Sprache:	eng
Schlagworte:	Adsorption Carbon Dioxide - chemistry Coordination Complexes - chemistry Dimerization Models, Molecular Nitrobenzenes - chemistry Porosity Ruthenium - chemistry Surface Properties
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A porous one-dimensional coordination chain compound, [Ru(2)(p-F-PhCO(2))(4)(phz)] (; p-F-PhCO(2)(-) = para-fluorobenzoate; phz = phenazine) derived by drying its nitrobenzene-solvated compound, specifically adsorbs CO(2) at 195 K in a stepwise sorption manner.
ISSN:	1364-548X
DOI:	10.1039/c2cc36153a