Guest-mediated switching of the assembly state of a water-soluble deep-cavity cavitand

Guest-mediated switching of the assembly state of a water-soluble deep-cavity cavitand

Deep-cavity cavitand TEMOA (2) is shown to assemble via the hydrophobic effect into tetrameric and hexameric assemblies. With inner volumes of 1400-1500 Å(3) and 3200-3700 Å(3) respectively, these well-defined and mono-dispersed assemblies represent the largest of their type to date.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (14), p.1395-1397
Hauptverfasser: Gan, Haiying, Gibb, Bruce C
Format: Artikel
Sprache:eng
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Zusammenfassung:Deep-cavity cavitand TEMOA (2) is shown to assemble via the hydrophobic effect into tetrameric and hexameric assemblies. With inner volumes of 1400-1500 Å(3) and 3200-3700 Å(3) respectively, these well-defined and mono-dispersed assemblies represent the largest of their type to date.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc38227j