Palladium-Catalyzed ortho-CH-Bond Oxygenation of Aromatic Ketones

A palladium-catalyzed C(sp2)–H bond oxygenation reaction is described. This protocol represents the first example of a C–H bond cleavage/C–O bond formation sequence, by employing a ketone moiety as the directing group. With this new catalytic method, a variety of ortho-acylphenols can be easily acce...

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Veröffentlicht in:	Organic letters 2013-01, Vol.15 (2), p.270-273
Hauptverfasser:	Choy, Pui Ying, Kwong, Fuk Yee
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Combinatorial Chemistry Techniques Ketones - chemistry Molecular Structure Oxidation-Reduction Palladium - chemistry Phenols - chemical synthesis Phenols - chemistry Stereoisomerism
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