Synthesis of Meso-Halogenated BODIPYs and Access to Meso-Substituted Analogues

Synthesis of Meso-Halogenated BODIPYs and Access to Meso-Substituted Analogues

8-Halogenated boradiaza-s-indacenes can be efficiently prepared from dipyrrylketones. The new dyes react smoothly with nucleophiles to yield N-, O-, and S-substituted chromophores, as well as transition-metal-catalyzed cross-coupling reactions. The nature of the new substitutent has a strong influen...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organic letters 2012-12, Vol.14 (24), p.6150-6153
Hauptverfasser: Leen, Volker, Yuan, Peijia, Wang, Lina, Boens, Noël, Dehaen, Wim
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:8-Halogenated boradiaza-s-indacenes can be efficiently prepared from dipyrrylketones. The new dyes react smoothly with nucleophiles to yield N-, O-, and S-substituted chromophores, as well as transition-metal-catalyzed cross-coupling reactions. The nature of the new substitutent has a strong influence on the spectral properties of the dyes.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol3028225