2-Amino-pyridinium trans-diaqua-bis-(oxalato-κ(2)O,O)chromate(III)

In the title hybrid salt, (C(5)H(7)N(2))[Cr(H(2)O)(2)(C(2)O(4))(2)], the Cr(III) ion is coordinated in a slightly distorted octa-hedral environment by four O atoms from two oxalate ligands in the equatorial plane and by two water O atoms in the axial sites. The 2-amino-pyridinium cation is disordere...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-11, Vol.68 (Pt 11), p.m1325-m1326
Hauptverfasser: Nenwa, Justin, Bebga, Gouet, Martin, Signé, Bélombé, Michel M, Mbarki, Mohammed, Fokwa, Boniface P T
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title hybrid salt, (C(5)H(7)N(2))[Cr(H(2)O)(2)(C(2)O(4))(2)], the Cr(III) ion is coordinated in a slightly distorted octa-hedral environment by four O atoms from two oxalate ligands in the equatorial plane and by two water O atoms in the axial sites. The 2-amino-pyridinium cation is disordered over two sets of sites in a 0.800 (7):0.200 (7) ratio. In the crystal, N-H⋯O and O-H⋯O hydrogen bonds connect the components into a three-dimensional network. The crystal studied was an inversion twin with components in a ratio 0.75 (2):0.25 (2).
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812040950