Functionalized ionic liquids with highly polar polyhydroxylated appendages and their rapid synthesis via thiol-ene click chemistry

The thiol-ene ‘click’ reaction of 1-thioglycerol with ionic liquids incorporating cations bearing appended vinyl- and/or allyl groups is a versatile, single-step means for their conversion into derivatives bearing up to eight hydroxyl groups per cation.

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Tetrahedron letters 2011-10, Vol.52 (40), p.5173-5175
Hauptverfasser:	O’Brien, Richard A., Mirjafari, Arsalan, Jajam, Vijayakumari, Capley, Erin N., Stenson, Alexandra C., West, Kevin N., Davis, James H.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings Indexing in process Organic chemistry Preparations and properties
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	The thiol-ene ‘click’ reaction of 1-thioglycerol with ionic liquids incorporating cations bearing appended vinyl- and/or allyl groups is a versatile, single-step means for their conversion into derivatives bearing up to eight hydroxyl groups per cation.
ISSN:	0040-4039 1873-3581
DOI:	10.1016/j.tetlet.2011.07.126