Steam effects over Pd/Ce0.67Zr0.33O2-Al2O3 three-way catalyst
Ceria-zirconia-alumina (CZA) solid solution was prepared by sol-gel method in the present study. 0.5 wt.% Pd supported on CZA was prepared by incipient wetness impregnation. The steam effects for CO and C3H8 oxidation, three-way catalytic activity and stoichiometric window property were studied. The...
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Veröffentlicht in: | Journal of rare earths 2012-08, Vol.30 (8), p.748-752 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Ceria-zirconia-alumina (CZA) solid solution was prepared by sol-gel method in the present study. 0.5 wt.% Pd supported on CZA was prepared by incipient wetness impregnation. The steam effects for CO and C3H8 oxidation, three-way catalytic activity and stoichiometric window property were studied. The light-off temperature of the CO oxidation reaction shifted to a lower temperature due to the water-gas shift (WGS) reactions. The oxidation of C3H8 was enhanced due to the steam reforming (SR) reactions. The steam promoted the C3H8 oxidation and NO reduction in three-way catalytic reaction. The amplitude of stoichiometric window was amplified by the addition of water to the feed stream. |
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ISSN: | 1002-0721 2509-4963 |
DOI: | 10.1016/S1002-0721(12)60123-9 |