Multipolymers with Fischer-Tropsch olefins

Multipolymers consisting of ethylene, 1‐heptene, 3‐methylpentene and 4‐methylpentene were prepared with a heterogeneous Ziegler‐Natta catalyst. The polymers were prepared in such a way that the molar fraction of the comonomers remained the same. Copolymers of ethylene/1‐heptene and ethylene/4‐methyl...

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Veröffentlicht in:Macromolecular symposia. 2003-03, Vol.193 (1), p.13-28
Hauptverfasser: Tincul, Ioan, Smith, Jaco, van Zyl, Pieter
Format: Artikel
Sprache:eng
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Zusammenfassung:Multipolymers consisting of ethylene, 1‐heptene, 3‐methylpentene and 4‐methylpentene were prepared with a heterogeneous Ziegler‐Natta catalyst. The polymers were prepared in such a way that the molar fraction of the comonomers remained the same. Copolymers of ethylene/1‐heptene and ethylene/4‐methylpentene were prepared in order to study the changes in polymer characteristics as one moves from an ethylene/linear alpha olefin copolymer through ethylene multipolymers to an ethylene/4‐methylpentene copolymer. The mechanical, rheological and application properties showed expected trends.
ISSN:1022-1360
1521-3900
DOI:10.1002/masy.200390047