Trapping {BW12}2 tungstoborate: synthesis and crystal structure of hybrid [{(H2BW12O42)2O}{Mo6O6S6(OH)4(H2O)2}]14- anion

Trapping {BW12}2 tungstoborate: synthesis and crystal structure of hybrid [{(H2BW12O42)2O}{Mo6O6S6(OH)4(H2O)2}]14- anion

Reaction between monolacunary {BW(11)} tungstoborate and oxothiocationic building block, {Mo(2)O(2)S(2)}, results in the formation of a new polyoxothiometalate with a unique architecture in which two [H(2)BW(12)O(43)](9-) tungstoborate subunits are linked together with a hexamolybdate [Mo(V)(6)O(6)S...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2012-12, Vol.41 (48), p.14484-14486
Hauptverfasser: Korenev, V S, Abramov, P A, Vicent, C, Mainichev, D A, Floquet, S, Cadot, E, Sokolov, M N, Fedin, V P
Format: Artikel
Sprache:eng
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Zusammenfassung:Reaction between monolacunary {BW(11)} tungstoborate and oxothiocationic building block, {Mo(2)O(2)S(2)}, results in the formation of a new polyoxothiometalate with a unique architecture in which two [H(2)BW(12)O(43)](9-) tungstoborate subunits are linked together with a hexamolybdate [Mo(V)(6)O(6)S(6)(OH)(4)(H(2)O)(2)](2+) bridge.
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt31512b