Reaction kinetics of selected micropollutants in ozonation and advanced oxidation processes

Second-order reaction rate constants of micropollutants with ozone (kO3) and hydroxyl radicals (kOH) are essential for evaluating their removal efficiencies from water during ozonation and advanced oxidation processes. Kinetic data are unavailable for many of the emerging micropollutants. Twenty-four micropollutants with very diverse structures and applications including endocrine disrupting compounds, pharmaceuticals, and personal care products were selected, and their kO3 and kOH values were determined using bench-scale reactors (at pH 7 and T = 20 °C). Reactions with molecular ozone are highly selective as indicated by their kO3 values ranging from 10−2–107 M−1 s−1. The general trend of ozone reactivity can be explained by micropollutant structures in conjunction with the electrophilic nature of ozone reactions. All of the studied compounds are highly reactive with hydroxyl radicals as shown by their high kOH values (108–1010 M−1 s−1) even though they are structurally very diverse. For compounds with a low reactivity toward ozone, hydroxyl radical based treatment such as O3/H2O2 or UV/H2O2 is a viable alternative. This study contributed to filling the data gap pertaining kinetic data of organic micropollutants while confirming results reported in the literature where available. [Display omitted] ► A group of structural diverse micropollutants was selected for a kinetic study. ► The rate constants of 24 micropollutants in ozonation and AOPs were reported. ► Reactivity toward ozone was linked to the structural features of micropollutants. ► Fill the gap in the kinetic database for emerging micropollutants oxidation.